Catalog # 07-1717 (9R)-9-Amino-cinchonan-6'-ol, min. 90%

These amino-cinchonnane compounds behave as pseudoenantiomers, generally granting access to both enantiomers of a given transformation. Technical notes: 1. [2+3]-dipolar cycloaddition of cyclic enones. 2. (-activation of α,β-unsaturated carbonyl groups. a.) vinylogous α-ketol rearrangement. b.) vinylogous Michael addition of β-substituted α,β-unsaturated cyclohexanones. c.) Formal (-alkylation by SN1 reaction of diarylmethanol with α-branched aldehydes. 3. Michael addition a.) α-nitroacetate to α,β-unsaturated ketones. b.) Diastereodivergent Michael addition to α-substituted, α,β-unsaturated ketones. 4. α-benzoyloxylation of α-branched aldehydes. 5. [4+2]-cycloadditions of β-substituted α,β-unsaturated cyclohexanones with polyconjugated malonitriles