THE NUCLEATION AND GROWTH OF SILICON NANOFILMS IN SUPERCOOLED LIQUID/SOLID PHASE

The formation of silicon nanofilms can be described using an approach of nucleation and island growth mechanism with enhanced supercooling. The theoretically derived parameters (∆G, ∆G*, r*, ∆Gv, ∆T) were found to be in the acceptable ranges that, Si nanofilms resembling 8 nm quantum dots could be fabricated on the substrate at extremely low nucleation rates. A Volmer-Weber growth model was used to explain the growth mode, initially by the aggregation of nuclei which increase in size leading to a liquid/solid phase transition. The resulting Si nanofilms were expected to be in an unwetting oval-shaped due to stronger nuclei-nuclei interactions