ABSTRACT: A series of all-thiol stabilized bimetallic Au−Cu nanoclusters, [Au12+nCu32(SR)30+n]4 − (n = 0, 2, 4, 6 and SR = SPhCF3), are successfully synthesized and characterized by X-ray single-crystal analysis and density functional theory (DFT) calculations. Each cluster consists of a Keplerate two-shel
X-ray crystallography has been fundamental in discovering fine structural features of ultrasmall gol...
New low-energy atomic structures of the thiolate-protected gold nanoparticle Au68(SH)32 are uncovere...
The larger size gold nanoparticles typically adopt a face-centered cubic (fcc) atomic packing, while...
A series of all-thiol stabilized bimetallic Au–Cu nanoclusters, [Au<sub>12+<i>n</i></sub>Cu<sub>32</...
Three novel bimetallic Au-Cu nanoclusters stabilized by a mixed layer of thiolate and phosphine liga...
Three novel bimetallic Au-Cu nanoclusters stabilized by a mixed layer of thiolate and phosphine liga...
A particularly stable thiolate-protected gold nanocluster, Au-25(SR)(18), was structurally character...
An intermetallic nanocluster containing 44 metal atoms, Au24Ag20(2-SPy)(4)(PhC C)(20)C-l2, was succe...
Unlike bulk materials, the physicochemical properties of nano-sized metal clusters can be strongly d...
Thiolate protected gold nanoclusters have gained substantial attention due to their atomically preci...
X-ray crystallography has been fundamental in discovering fine structural features of ultrasmall gol...
Herein, we report the synthesis and atomic structures of the cluster-assembled Cu<sub><i>x</i></sub>...
Precise control of the growth of thiolate-protected gold nanoclusters is a prerequisite for their ap...
We report the synthesis and total structure determination of a Au<sub>24</sub> nanocluster protected...
A structure evolution map of face-centered cubic (fcc)-structured thiolate-ligand protected gold nan...
X-ray crystallography has been fundamental in discovering fine structural features of ultrasmall gol...
New low-energy atomic structures of the thiolate-protected gold nanoparticle Au68(SH)32 are uncovere...
The larger size gold nanoparticles typically adopt a face-centered cubic (fcc) atomic packing, while...
A series of all-thiol stabilized bimetallic Au–Cu nanoclusters, [Au<sub>12+<i>n</i></sub>Cu<sub>32</...
Three novel bimetallic Au-Cu nanoclusters stabilized by a mixed layer of thiolate and phosphine liga...
Three novel bimetallic Au-Cu nanoclusters stabilized by a mixed layer of thiolate and phosphine liga...
A particularly stable thiolate-protected gold nanocluster, Au-25(SR)(18), was structurally character...
An intermetallic nanocluster containing 44 metal atoms, Au24Ag20(2-SPy)(4)(PhC C)(20)C-l2, was succe...
Unlike bulk materials, the physicochemical properties of nano-sized metal clusters can be strongly d...
Thiolate protected gold nanoclusters have gained substantial attention due to their atomically preci...
X-ray crystallography has been fundamental in discovering fine structural features of ultrasmall gol...
Herein, we report the synthesis and atomic structures of the cluster-assembled Cu<sub><i>x</i></sub>...
Precise control of the growth of thiolate-protected gold nanoclusters is a prerequisite for their ap...
We report the synthesis and total structure determination of a Au<sub>24</sub> nanocluster protected...
A structure evolution map of face-centered cubic (fcc)-structured thiolate-ligand protected gold nan...
X-ray crystallography has been fundamental in discovering fine structural features of ultrasmall gol...
New low-energy atomic structures of the thiolate-protected gold nanoparticle Au68(SH)32 are uncovere...
The larger size gold nanoparticles typically adopt a face-centered cubic (fcc) atomic packing, while...