Add to ORKGMixtures of cyanogen and nitrous oxide diluted in argon were shock-heated to measure the rate constants of (2) C2N2 + O- » CN + NCO (3) CN + 0 — CO(u) + N A broad-band mercury lamp was used to measure CN in absorption at 388 nm [B22*(u = 0) «- X*1~(v = 0)], and the spectral coincidence of a CO infrared absorp tion line [u(2 <- 1), J(37 ♦- 38)] with a CO laser line [i>(6- » 5), J(15-> 16)] was ex ploited to monitor CO in absorption. The CO measurement established that reaction (3) produces CO in excited vibrational states. A computer fit of the experiments near 2000 K led to k2 = 10llTO+OM-ol91cm7raol-s *3 = 10l3M±028cm7mol-s An additional measurement of NO via infrared absorption led to an estimate of the ratio ks/kt: (5) NCO + O —...
Experiments were conducted using a custom double-stirred tank reactor to determine the rate constant...
A quadrupole mass-filter was built and coupled to a shock tube in or-der to study high temperature g...
Author Institution: Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000...
Shock tube experiments are carried out to study the physical and chemical processes during a vehicle...
International audienceThe reaction between atomic carbon in its ground electronic state, C(3P), and ...
The thermal decomposition of cyanonitrene, NCN, was studied behind reflected shock waves in the temp...
The chemical kinetics of cyclopentanone, an attractive fuel for spark ignition engines, was studied ...
Mixtures of cyanogen and nitrous oxide diluted in argon were shock heated to measure the ratio of th...
The role of active nitrogen in exciting high vibrational levels of the ground electronic state of ca...
The thermal decomposition of three ethyl esters, ethyl formate (C<sub>3</sub>H<sub>6</sub>O<sub>2</s...
The chemical kinetics of cyclopentanone, an attractive fuel for spark ignition engines, was studied ...
CO concentration and gas temperature distribution are diagnosed behind a strong shock wave simulatin...
The C_2+NO reaction has been studied by observing the CN (B-X) and CN (A-X) chmiluminescence. Experi...
A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation...
International audienceMore than 70 molecules of varied nature have been identified in the envelopes ...
Experiments were conducted using a custom double-stirred tank reactor to determine the rate constant...
A quadrupole mass-filter was built and coupled to a shock tube in or-der to study high temperature g...
Author Institution: Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000...
Shock tube experiments are carried out to study the physical and chemical processes during a vehicle...
International audienceThe reaction between atomic carbon in its ground electronic state, C(3P), and ...
The thermal decomposition of cyanonitrene, NCN, was studied behind reflected shock waves in the temp...
The chemical kinetics of cyclopentanone, an attractive fuel for spark ignition engines, was studied ...
Mixtures of cyanogen and nitrous oxide diluted in argon were shock heated to measure the ratio of th...
The role of active nitrogen in exciting high vibrational levels of the ground electronic state of ca...
The thermal decomposition of three ethyl esters, ethyl formate (C<sub>3</sub>H<sub>6</sub>O<sub>2</s...
The chemical kinetics of cyclopentanone, an attractive fuel for spark ignition engines, was studied ...
CO concentration and gas temperature distribution are diagnosed behind a strong shock wave simulatin...
The C_2+NO reaction has been studied by observing the CN (B-X) and CN (A-X) chmiluminescence. Experi...
A diagnostic technique for monitoring the concentration of NO using absorption of CO laser radiation...
International audienceMore than 70 molecules of varied nature have been identified in the envelopes ...
Experiments were conducted using a custom double-stirred tank reactor to determine the rate constant...
A quadrupole mass-filter was built and coupled to a shock tube in or-der to study high temperature g...
Author Institution: Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973-5000...