Add to ORKGAbstract: A variety of substituted N-diphenylphosphinyl imines were hydrogenated using Pd(CF3CO2)2/(S)-SEGPHOS as a catalyst with high enantioselectivities (86.7%–98.6 % ee). Key words: palladium, asymmetric synthesis, hydrogenation, N-diphenylphosphinyl imines Transition-metal-catalyzed asymmetric synthesis is a powerful and commonly used method for preparing a wide range of enantiomerically pure compounds.1 Among organo-transition-metal compounds, Pd complexes have become indispensable tools for both common and state-of-the art organic synthesis.2 Although a large number of Pd-based catalytic systems have been developed for many kinds of reactions, Pd chemistry has still not achieved its full potential. So, the search for improved Pd-cata...
A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient ca...
Using pd(cf(3)co(2))(2)/(S,S)-f-Binaphane as the catalyst, an efficient enantioselective Synthesis o...
This thesis describes synthesis of new chiral N,P ligands and their evaluation in two types of asymm...
Abstract: Homogenous palladium-catalyzed asymmetric hydroge-nation of C=C double bond of a,b-unsatur...
Catalytic asymmetric hydrogenations of prochiral unsaturated compounds, such as olefins, ketones, an...
A variety of substituted N-diphenylphosphinyl imines were hydrogenated using Pd(CF3CO2)(2)/(S)-SEGPH...
Chiral molecules exist in two different forms called enantiomers, which are non-superimposable mirro...
The transition metal catalyzed asymmetric hydrogenation of unsaturated compounds arguably presents o...
Pd/bisphosphines complexes are highly effective catalysts for asymmetric hydrogenation of activated ...
This thesis summarizes the author’s graduate research on phosphorus ligands synthesis and catalytic ...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
Summary: In transition metal-catalyzed asymmetric synthesis, enantioselectivity strongly depends on ...
The research described in this thesis is directed toward the efficient, enantioselective synthesis o...
A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient ca...
Using pd(cf(3)co(2))(2)/(S,S)-f-Binaphane as the catalyst, an efficient enantioselective Synthesis o...
This thesis describes synthesis of new chiral N,P ligands and their evaluation in two types of asymm...
Abstract: Homogenous palladium-catalyzed asymmetric hydroge-nation of C=C double bond of a,b-unsatur...
Catalytic asymmetric hydrogenations of prochiral unsaturated compounds, such as olefins, ketones, an...
A variety of substituted N-diphenylphosphinyl imines were hydrogenated using Pd(CF3CO2)(2)/(S)-SEGPH...
Chiral molecules exist in two different forms called enantiomers, which are non-superimposable mirro...
The transition metal catalyzed asymmetric hydrogenation of unsaturated compounds arguably presents o...
Pd/bisphosphines complexes are highly effective catalysts for asymmetric hydrogenation of activated ...
This thesis summarizes the author’s graduate research on phosphorus ligands synthesis and catalytic ...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
The work presented in this thesis concerns asymmetric catalysis using chiral N,P-ligands and iridium...
Summary: In transition metal-catalyzed asymmetric synthesis, enantioselectivity strongly depends on ...
The research described in this thesis is directed toward the efficient, enantioselective synthesis o...
A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient ca...
Using pd(cf(3)co(2))(2)/(S,S)-f-Binaphane as the catalyst, an efficient enantioselective Synthesis o...
This thesis describes synthesis of new chiral N,P ligands and their evaluation in two types of asymm...