Add to ORKGA new class of flavone which possess an aryl radical substituted in the A ring via C-C bond, arylchrysin analogues, has been synthesized from chrysin by Suzuki coupling reaction in three to five steps. Firstly, methylation or benzylation reaction was applied on chrysin to protect hydroxyl phenol moiety. Then, halogenation by iodine or bromine in anhydrous acetic acid was performed to obtain halogenated chrysin. Finally, intermediate compounds were treated with areneboronic derivatives catalyzed by palladium tetrakits to generate arylchrysin analogues with high yields. Key words: arylchrysin, carbon-carbon coupling Suzuki reaction
International audienceA series of 4′-alkyl-2′-hydroxyacetophenones were prepared by Suzuki cross-cou...
© CSIRO 2008Acylation of 1,3,5-tribenzyloxybenzene with alkoxy-substituted phenylpropioloyl chloride...
Recently, the coupling reactions of aryl chlorides have been widely used in the syntheses of interme...
A variety of 4'- and 3-C-aryl-quercetin derivatives were conveniently synthesized via Suzuki-Myaura ...
Herein, we report the use of the Suzuki–Miyaura cross-coupling reaction for the preparation of a lib...
This thesis includes regioselective palladium(0)-catalyzed Suzuki cross-coupling reactions of quinol...
The synthesis of 4-aryl-5-methoxy-, 5-aryl-4-methoxy- and 4,5-diaryl-3(2H)-pyridazinones via Suzuki ...
Isoflavones were synthesized via Suzuki–Miyaura coupling of 3-iodochromones and para-methoxybenzene-...
Palladium-catalysed coupling reactions have gained importance as a tool for the production of pharma...
Development of synthetic methods for silole-containing or -fused polycyclic aromatic compounds has b...
Structurally novel carbohydrate–flavone and –chromone derivatives with an unsaturated carbon bridge ...
On treatment with trimethyl borate sodium acetylide undergoes a palladium-catalyzed cross coupling w...
A new general method for the synthesis of chrysophanol, rhein, islandicin, emodin and physcion, star...
The use of aryl vinyl ketones in the Heck reaction for the synthesis of flavonoids was previously de...
Chromans and quinolines can be found in the core structures of many biologically active natural prod...
International audienceA series of 4′-alkyl-2′-hydroxyacetophenones were prepared by Suzuki cross-cou...
© CSIRO 2008Acylation of 1,3,5-tribenzyloxybenzene with alkoxy-substituted phenylpropioloyl chloride...
Recently, the coupling reactions of aryl chlorides have been widely used in the syntheses of interme...
A variety of 4'- and 3-C-aryl-quercetin derivatives were conveniently synthesized via Suzuki-Myaura ...
Herein, we report the use of the Suzuki–Miyaura cross-coupling reaction for the preparation of a lib...
This thesis includes regioselective palladium(0)-catalyzed Suzuki cross-coupling reactions of quinol...
The synthesis of 4-aryl-5-methoxy-, 5-aryl-4-methoxy- and 4,5-diaryl-3(2H)-pyridazinones via Suzuki ...
Isoflavones were synthesized via Suzuki–Miyaura coupling of 3-iodochromones and para-methoxybenzene-...
Palladium-catalysed coupling reactions have gained importance as a tool for the production of pharma...
Development of synthetic methods for silole-containing or -fused polycyclic aromatic compounds has b...
Structurally novel carbohydrate–flavone and –chromone derivatives with an unsaturated carbon bridge ...
On treatment with trimethyl borate sodium acetylide undergoes a palladium-catalyzed cross coupling w...
A new general method for the synthesis of chrysophanol, rhein, islandicin, emodin and physcion, star...
The use of aryl vinyl ketones in the Heck reaction for the synthesis of flavonoids was previously de...
Chromans and quinolines can be found in the core structures of many biologically active natural prod...
International audienceA series of 4′-alkyl-2′-hydroxyacetophenones were prepared by Suzuki cross-cou...
© CSIRO 2008Acylation of 1,3,5-tribenzyloxybenzene with alkoxy-substituted phenylpropioloyl chloride...
Recently, the coupling reactions of aryl chlorides have been widely used in the syntheses of interme...