Conical intersections of potential energy surfaces widely appear in molecules which consist of more than two atoms. No conical intersections exist in the case of free diatomic molecules. We show here that diatomic molecules interacting with standing laser waves produce periodic arrays of conical intersections. At these laser-induced intersections the non-adiabatic effects are infinitely strong. The translational and rovibrational molecular motions become strongly coupled to each other and energy exchange between the various degrees of freedom influences the dynamics of the system. As an illustrative example, an effect of the laser-induced conical intersections on trapping of ultracold diatomic molecules by light is discussed. (Some figures ...
The strong coupling between intense laser fields and valence electrons in molecules causes distortio...
This concise book introduces and discusses the basic theory of conical intersections with applicatio...
Author Institution: Department of Chemistry, Temple University, Philadelphia, PA 19122Three-state co...
Nonadiabatic effects are ubiquitous in physics, chemistry and biology. They are strongly amplified b...
Potential energy surfaces for electronic states of molecules in strong electromagnetic fields can be...
It has already been shown that dressing of diatomic molecules by standing or running linear polarize...
It has already been shown that dressing of diatomic molecules by standing or running linear polarize...
Potential energy surfaces for electronic states of molecules in strong electromagnetic fields can be...
The concept of adiabatic electronic potential-energy surfaces, defined by the Born–Oppenheimer appro...
We find that energy surfaces of more than two atoms or molecules interacting via transition dipole-d...
We find that energy surfaces of more than two atoms or molecules interacting via transition dipole-d...
Conical intersections are degeneracies between multidimensional potential energy surfaces of molecul...
Light-induced nonadiabatic phenomena arise when molecules or molecular ensembles are exposed to reso...
We show that the simplest of existing molecules -- closed-shell diatomics not interacting with one a...
The strong coupling between intense laser fields and valence electrons in molecules causes distortio...
The strong coupling between intense laser fields and valence electrons in molecules causes distortio...
This concise book introduces and discusses the basic theory of conical intersections with applicatio...
Author Institution: Department of Chemistry, Temple University, Philadelphia, PA 19122Three-state co...
Nonadiabatic effects are ubiquitous in physics, chemistry and biology. They are strongly amplified b...
Potential energy surfaces for electronic states of molecules in strong electromagnetic fields can be...
It has already been shown that dressing of diatomic molecules by standing or running linear polarize...
It has already been shown that dressing of diatomic molecules by standing or running linear polarize...
Potential energy surfaces for electronic states of molecules in strong electromagnetic fields can be...
The concept of adiabatic electronic potential-energy surfaces, defined by the Born–Oppenheimer appro...
We find that energy surfaces of more than two atoms or molecules interacting via transition dipole-d...
We find that energy surfaces of more than two atoms or molecules interacting via transition dipole-d...
Conical intersections are degeneracies between multidimensional potential energy surfaces of molecul...
Light-induced nonadiabatic phenomena arise when molecules or molecular ensembles are exposed to reso...
We show that the simplest of existing molecules -- closed-shell diatomics not interacting with one a...
The strong coupling between intense laser fields and valence electrons in molecules causes distortio...
The strong coupling between intense laser fields and valence electrons in molecules causes distortio...
This concise book introduces and discusses the basic theory of conical intersections with applicatio...
Author Institution: Department of Chemistry, Temple University, Philadelphia, PA 19122Three-state co...