Journal of Power Sources 134 (2004) 324–330 Synthesis and electrochemical properties of mesoporous nickel oxide

Mesoporous Ni(OH)2 is synthesized using sodium dodecyl sulfate as a template and urea as a hydrolysis-controlling agent. Mesoporous NiO with a centralized pore-size distribution is obtained by calcining Ni(OH)2 at different temperatures. The BET specific surface area reaches 477.7 m2 g−1 for NiO calcined at 250 ◦C. Structure characterizations indicate a good mesoporous structure for the nickel oxide samples. Cyclic voltammetry shows the NiO to have good capacitive behaviour due to its unique mesoporous structure when using a large amount of NiO to fabricate the electrode. Compared with NiO prepared by dip-coating and cathodic precipitation methods, mesoporous NiO with a controlled pore structure can be used in much larger amounts to fabricate electrodes and still maintain a high specific capacitance and good capacitive behaviour