Mechanistic Studies of Proton Donor Coordination to Samarium Diiodide

UV-vis spectrum of SmI2 with increasing amounts of DGDE Cyclic volatammogram of SmI2 with increasing amounts of DG Cyclic voltammogram of SmI2 with increasing amounts of DGME Cyclic voltammogram of SmI2 with increasing amounts of DGDE Plot of Ln kobs vs. Ln [Diethylene Glycol] Plot of Ln kobs vs. Ln [Benzyl Bromide] in the SmI2:DG system Plot of t3/2/t1/2 vs. reaction order Determination of SmI2 reaction order in the SmI2:DG system Plot of Ln kobs vs. Ln [Diethylene Glycol Monomethyl Ether] Plot of Ln kobs vs. Ln [Benzyl Bromide] in the SmI2:DGME system Determination of SmI2 reaction order in the SmI2:DGME system Plot of Ln kobs vs. Ln [Diethylene Glycol Dimethyl Ether] Plot of Ln kobs vs. Ln [Benzyl Bromide] in the SmI2:DGDE system Determination of SmI2 reaction order in the SmI2:DGDE system Deuterium Isotope Effect Product characterization GC-MS with toluene as major product GC-MS with monodeuterated toluene as major product S1 GC-MS with bibenzyl as major product S1