Add to ORKGAbstract Recent work on the synthesis, structure, and chemical reactions of metalloboranes is reviewed. In the decaborane series, single—crystal X-ray studies indicate that the metal atom can be (a) fully incorporated within the borane cluster, (b) joined to the cluster by an exopolyhedral B-M-B bond in which the metal replaces a bridging proton, or (c) joined by a normal c B-M bond by replacement of a terminal hydrogen atom. Complexes of B10H122 with Fe; Zn, Cd, Hg; Mg; Al, Ga, In, Tl; and Sn are specifically discussed. In the pentaborane series numerous complexes have been prepared for a wide variety of transition metals and main group metals (Ti; Fe; Co, Rh
The goal of this research was to develop the metal atom reaction technique for the synthesis of new ...
Metallatricarbadecaboranes can be considered analogues of their corresponding metallocenes, but with...
The work described here consists of the synthesis and characterization of new materials utilizing po...
Abstract — The various synthetic routes to metalloboranes are systematically classified and assessed...
The goal of my research was to investigate the interaction of boron clusters with different types of...
Abstract- Recent work has shown that most transition metals and post-transition metals can be incorp...
The work described here consists of the synthesis and characterization of new borane cluster compoun...
The properties of some new metallacarboranes are described in this thesis, along with the results of...
International audienceMolecular metallaboranes, which feature complexes with M-B rather than M-C bon...
Molecular metallaboranes, which feature complexes with M–B rather than M–C bonds, constitute a class...
Abstract: A summary of the latest results in the authors ’ laboratories covering three areas is pres...
Ten years after the discovery of metallocarboranes, this field of chemistry is still advancing at a ...
Metallatricarbadecaboranes can be considered analogues of their corresponding metallocenes, but with...
Icosahedral 2,4-dicarba-1-ferraboranes with η6-bonded benzene, toluene, o-xylene, or naphthalene lig...
The goal of this research was to develop the metal atom reaction technique for the synthesis of new ...
The goal of this research was to develop the metal atom reaction technique for the synthesis of new ...
Metallatricarbadecaboranes can be considered analogues of their corresponding metallocenes, but with...
The work described here consists of the synthesis and characterization of new materials utilizing po...
Abstract — The various synthetic routes to metalloboranes are systematically classified and assessed...
The goal of my research was to investigate the interaction of boron clusters with different types of...
Abstract- Recent work has shown that most transition metals and post-transition metals can be incorp...
The work described here consists of the synthesis and characterization of new borane cluster compoun...
The properties of some new metallacarboranes are described in this thesis, along with the results of...
International audienceMolecular metallaboranes, which feature complexes with M-B rather than M-C bon...
Molecular metallaboranes, which feature complexes with M–B rather than M–C bonds, constitute a class...
Abstract: A summary of the latest results in the authors ’ laboratories covering three areas is pres...
Ten years after the discovery of metallocarboranes, this field of chemistry is still advancing at a ...
Metallatricarbadecaboranes can be considered analogues of their corresponding metallocenes, but with...
Icosahedral 2,4-dicarba-1-ferraboranes with η6-bonded benzene, toluene, o-xylene, or naphthalene lig...
The goal of this research was to develop the metal atom reaction technique for the synthesis of new ...
The goal of this research was to develop the metal atom reaction technique for the synthesis of new ...
Metallatricarbadecaboranes can be considered analogues of their corresponding metallocenes, but with...
The work described here consists of the synthesis and characterization of new materials utilizing po...