EFFECT OF ORGANIC ACIDS IN CO2 CORROSION

In the majority of the published work related to organic acid corrosion of mild steel, the focus is on acetic acid due to its prevalence in a typical organic acid mix seen in the field. In this work, the electrochemical behaviour of X65 carbon steel in the presence of other important organic acids (formic and propionic) and the effect that these have in the growth and protectiveness of iron carbonate (FeCO3) scale have been investigated. It was found that very little difference exists in electrochemical behaviour of the formic, acetic and propionic acids when it comes to CO2 corrosion of mild steel, given that the pH and concentrations of the undissociated organic acids is the same. Just like the other two weak organic acids, formic acid increases the corrosion rate due to an additional cathodic reaction: direct reduction of undissociated formic acid; this reaction is very temperature sensitive and may be limited by diffusion. The presence of organic acids makes it harder for protective iron carbonate scales to form due to a “scale undermining” effect. The scale precipitation rate is not directly affected, however, the time it takes to reach low corrosion rates is