Post functionalizaion of aryl ether perfluorocyclobutyl (PFCB) polymers with fluoroalkyl side chains was accomplished with Umemoto's FITS reagents. The fluoroalkylated PFCB polymers (20 % functionalized) showed increases in both hydrophobicity and oleophobicity. Static contact angle for hexadecane was increased after fluoroalkylation from 0o to greater than 30o for both PFCB polymers. Increased oil repellency makes these materials potential candidates for coatings applications
The high electronegativity and small size of the fluorine atom and the high stability of C-F bonds i...
Fluoropolymers are currently used in many high technology areas such as aerospace, aeronautic (seals...
This paper describes partially fluorinated poly- p -xylylenes prepared by CVD polymerization. The sy...
The cyclopolymerization of aromatic trifluorovinyl ether (TFVE) monomers offers a versatile route to...
A new structural fluorine-containing methacrylate monomer CH2=C(CH3)COOC⁻(CF3)2CF2CF2CF3 (5) w...
Original perfluoropolyethers (PFPE)-based oligomeric polyesters (FOPs) of different macromolecular a...
International audienceIn order to produce extremely high oleophobic properties with a low fluorine c...
In this study, three types of fluorinated polyacrylates (PBFB, PBFS and PMFA) were synthesized by 4-...
Perfluoropolyalkylethers (PFPAEs) are a class of fluorinated polymers having −OCF2–, −OCF2CF2–, and ...
International audienceIn order to find alternatives to long perfluorinated chains, due to their bioa...
For decades, water and oil repellency of engineering thermoplastics has been achieved with introduct...
For decades, water and oil repellency of engineering thermoplastics has been achieved with the intro...
Two kinds of fluorinated polymers were synthesized: an acrylate polymer having a fluorinated triethy...
Polymer surface modification can be accomplished by several techniques including chemical reaction a...
Technological advances in aerospace, automotive, electronics and other high-technology industries co...
The high electronegativity and small size of the fluorine atom and the high stability of C-F bonds i...
Fluoropolymers are currently used in many high technology areas such as aerospace, aeronautic (seals...
This paper describes partially fluorinated poly- p -xylylenes prepared by CVD polymerization. The sy...
The cyclopolymerization of aromatic trifluorovinyl ether (TFVE) monomers offers a versatile route to...
A new structural fluorine-containing methacrylate monomer CH2=C(CH3)COOC⁻(CF3)2CF2CF2CF3 (5) w...
Original perfluoropolyethers (PFPE)-based oligomeric polyesters (FOPs) of different macromolecular a...
International audienceIn order to produce extremely high oleophobic properties with a low fluorine c...
In this study, three types of fluorinated polyacrylates (PBFB, PBFS and PMFA) were synthesized by 4-...
Perfluoropolyalkylethers (PFPAEs) are a class of fluorinated polymers having −OCF2–, −OCF2CF2–, and ...
International audienceIn order to find alternatives to long perfluorinated chains, due to their bioa...
For decades, water and oil repellency of engineering thermoplastics has been achieved with introduct...
For decades, water and oil repellency of engineering thermoplastics has been achieved with the intro...
Two kinds of fluorinated polymers were synthesized: an acrylate polymer having a fluorinated triethy...
Polymer surface modification can be accomplished by several techniques including chemical reaction a...
Technological advances in aerospace, automotive, electronics and other high-technology industries co...
The high electronegativity and small size of the fluorine atom and the high stability of C-F bonds i...
Fluoropolymers are currently used in many high technology areas such as aerospace, aeronautic (seals...
This paper describes partially fluorinated poly- p -xylylenes prepared by CVD polymerization. The sy...