mi id

Univ ised f olyte e the resul fram a relationship between experimental results and the microscopic structure of interfaces between two immiscible electrolyte solutions (ITIES). taining a hydrophobic salt and an aqueous electrolyte of ITIES depends strongly on the nature of the ions [2,6–11]. Often the capacitance curves show a strong asymmetry as a function of the potential and essential [9–11,14–19]. It has been also shown that a thermally adsorption and ion association at the interface. The theory extends our recent studies [19], which have been focused on the effect of ion penetration into an ‘‘un-friendly medium’ ’ and described this effect within a perturbation approach. Here we overcome limitations of the perturbation approach that allows the treatment of experiments in which a measured capacitance differ