DEVELOPMENT OF INTERMIXED ZONES OF ALUMINA/ZIRCONIA IN THERMAL BARRIER COATING SYSTEMS

The mechanisms whereby intermixed zones of alumina and zirconia are formed at the interface between the metallic bond coat and the ceramic top coat (yttria-stabilized zirconia) in thermal barrier coating systems have been investigated. The results lead to the following mechanism for the formation of the zones. The predominant mechanism for intermixed zone formation involves formation of a metastable alumina polymorph (θ or γ) during TBC deposition, with a significant amount of zirconia dissolved in it. The outward growth also begins to incorporate zirconia particles, which initiates the formation of the intermixed zone. Upon thermal exposure, the metastable TGO continues to grow outward, extending the intermixed zone, and eventually transforms to the equilibrium α-Al2O3. The transformation to α-Al2O3 results in an increase in the volume fraction of zirconia in the intermixed zone as it is rejected from solution. Once the α-Al2O3 appears, subsequent TGO growth produces a columnar zone of the TGO without a second phase. When α-alumina was pre-formed on the bond coat, prior to TBC deposition, no intermixed zone was formed for Pt-modified aluminide bond coats