Abstract. The enthalpies of formation of RyR’1-yBa2Cu3Ox (R, R’=Y, Nd, Eu; y=0; 0,5) have been determined at 298K by solution calorimetry. These values were shown for YBa2Cu3Ox to depend on the oxygen stoichiometry of a sample. The results of thermodynamic investigations were found to be in good agreement with the data of the kinetic investigations of the Y(Ln) Ba2Cu3Ox formation reactions. This agreement is explained in the aspect of electronic structure of lanthanide atoms. 1
The Y-Ba-Cu-O system has been intensely studied since 1987 because of the discovery of superconducti...
Electromotive force (EMF) measurements using ZrO2 solid electrolyte were carried out in the Ba–Y–Cu–...
The rate of formation of YBa2Cu4O8 (124) by solid state reaction of YBa2Cu3O7-δ (123) with CuO ...
Solution-reaction calorimetry was used to determine the standard molar (p'=0.10 Mpa) enthalpies of f...
The general thermochemical reaction LnCl 3·6H 2O(c)+3Hthd(1)+73.92H 2O(1) = Ln(thd) 3(c) +3HCl·26.64...
The general thermochemical reaction LnCl3 . 6H2O(c) + 3Hthd(l) + 73.92H2O(l) = Ln(thd)3(c) + 3HCl . ...
The high temperature enthalpies of five rare earths were measured from 0 to 1100 deg C using a Bunse...
Thermal and spectroscopic studies on solid trivalent lanthanides and yttrium(III) α-hydroxyisobutyra...
The variation of equilibrium oxygen potential with oxygen concentration inYBa 2Cu3O7-δhas been measu...
The thermodynamics of the oxidation reaction of YBa2Cu3Ox have been studied using precision data for...
A family of lanthanide silicates adopts an oxyapatitelike structure with structural formula Ln9.33h0...
The variation of equilibrium oxygen potential with oxygen concentration in $YBa_2Cu_3O_{7-\delta}$ h...
The standard enthalpies of formation of yttrium alloys, Y Me (Me = Ru, Rh, Pd, Os, Ir, Pt) were dete...
Isothermal sections of the phase diagrams for the systems Ln-Pd-O (Ln = lanthanide element) at 1223 ...
The Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5 from component oxides have been mea...
The Y-Ba-Cu-O system has been intensely studied since 1987 because of the discovery of superconducti...
Electromotive force (EMF) measurements using ZrO2 solid electrolyte were carried out in the Ba–Y–Cu–...
The rate of formation of YBa2Cu4O8 (124) by solid state reaction of YBa2Cu3O7-δ (123) with CuO ...
Solution-reaction calorimetry was used to determine the standard molar (p'=0.10 Mpa) enthalpies of f...
The general thermochemical reaction LnCl 3·6H 2O(c)+3Hthd(1)+73.92H 2O(1) = Ln(thd) 3(c) +3HCl·26.64...
The general thermochemical reaction LnCl3 . 6H2O(c) + 3Hthd(l) + 73.92H2O(l) = Ln(thd)3(c) + 3HCl . ...
The high temperature enthalpies of five rare earths were measured from 0 to 1100 deg C using a Bunse...
Thermal and spectroscopic studies on solid trivalent lanthanides and yttrium(III) α-hydroxyisobutyra...
The variation of equilibrium oxygen potential with oxygen concentration inYBa 2Cu3O7-δhas been measu...
The thermodynamics of the oxidation reaction of YBa2Cu3Ox have been studied using precision data for...
A family of lanthanide silicates adopts an oxyapatitelike structure with structural formula Ln9.33h0...
The variation of equilibrium oxygen potential with oxygen concentration in $YBa_2Cu_3O_{7-\delta}$ h...
The standard enthalpies of formation of yttrium alloys, Y Me (Me = Ru, Rh, Pd, Os, Ir, Pt) were dete...
Isothermal sections of the phase diagrams for the systems Ln-Pd-O (Ln = lanthanide element) at 1223 ...
The Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5 from component oxides have been mea...
The Y-Ba-Cu-O system has been intensely studied since 1987 because of the discovery of superconducti...
Electromotive force (EMF) measurements using ZrO2 solid electrolyte were carried out in the Ba–Y–Cu–...
The rate of formation of YBa2Cu4O8 (124) by solid state reaction of YBa2Cu3O7-δ (123) with CuO ...