Add to ORKGAbstract: By appropriate choice or design of ligands it is possible to place main group elements in low coordination number and/or low oxidation state environments. For example, reactive main group entities such as phosphinidenes and arsenidenes can be stabilized by coordination to carbenes; they can also serve as ligands in d- and f-block metal complexes. Main group fragments can also be incorporated into ring systems and clusters
Klaus TheopoldRedox active ligands, i.e. ligands that can be reduced or oxidized, are of considerabl...
The activation of small molecule is a topic of high current interest. A variety of homogeneous end h...
This thesis focuses on the studies of N-heterocyclic carbnene (NHC)-coordinated main group element f...
Since the discovery that main group elements can mimic transition metals, efforts have focussed on h...
α-Diimine ligands, in particular 1,4-diazabutadiene (dad) and bis(iminoacenaphthene) (bian) derivati...
A class of transition-metal and main group compounds will be synthesized and investigated for their ...
Abstract — Phosphinidene—, arsinidene — and stibinidene—complexes LnMX(R)_ _ MLn (X = P, As, Sb) con...
The thesis is about the preparation and characterization of highly reactive compounds. These are use...
Recent years have witnessed remarkable advances in radical reactions involving main‐group metal comp...
Jutzi P. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 19...
The choice of both ligand and metal centre plays a critical role in the reactivity of a complex. No...
1v. of offprintsTitle page, contents and abstract only. The complete thesis in print form is availab...
The first part of this work discusses a series of experiments involving trans-azobenzene, PhN=NPh, a...
Two major aspects of coordination/organometallic chemistry are discussed in this article: (i) the us...
Carbenes have a long history of being classed as highly reactive species, whose isolation was deemed...
Klaus TheopoldRedox active ligands, i.e. ligands that can be reduced or oxidized, are of considerabl...
The activation of small molecule is a topic of high current interest. A variety of homogeneous end h...
This thesis focuses on the studies of N-heterocyclic carbnene (NHC)-coordinated main group element f...
Since the discovery that main group elements can mimic transition metals, efforts have focussed on h...
α-Diimine ligands, in particular 1,4-diazabutadiene (dad) and bis(iminoacenaphthene) (bian) derivati...
A class of transition-metal and main group compounds will be synthesized and investigated for their ...
Abstract — Phosphinidene—, arsinidene — and stibinidene—complexes LnMX(R)_ _ MLn (X = P, As, Sb) con...
The thesis is about the preparation and characterization of highly reactive compounds. These are use...
Recent years have witnessed remarkable advances in radical reactions involving main‐group metal comp...
Jutzi P. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 19...
The choice of both ligand and metal centre plays a critical role in the reactivity of a complex. No...
1v. of offprintsTitle page, contents and abstract only. The complete thesis in print form is availab...
The first part of this work discusses a series of experiments involving trans-azobenzene, PhN=NPh, a...
Two major aspects of coordination/organometallic chemistry are discussed in this article: (i) the us...
Carbenes have a long history of being classed as highly reactive species, whose isolation was deemed...
Klaus TheopoldRedox active ligands, i.e. ligands that can be reduced or oxidized, are of considerabl...
The activation of small molecule is a topic of high current interest. A variety of homogeneous end h...
This thesis focuses on the studies of N-heterocyclic carbnene (NHC)-coordinated main group element f...