Abstract- A review is given on controversial gelation problems very close to the sol-gel transition. For several quantities the concept of critical exponents like and y is introduced. For example, the gel fraction vani— shes as c and the weight-average degree of polymerization diverges as where c is the small distance from the gel point. Classical theory (Flory, Stockmayer, Gordon,...) predicts =y=1 whereas recent percolation theories give =O.4, y=1.7. Who is right
ABSTRACT We report experimental data on gel fraction, gel equilibrium swelling, sol intrinsic viscos...
We develop a percolation model motivated by recent experimental studies of gels with active network ...
We develop a percolation model motivated by recent experimental studies of gels with active network ...
The critical behaviour of the elastic constant and the friction coefficient have been measured in th...
The critical behaviour of the elastic constant and the friction coefficient have been measured in th...
We study the elasticity behaviour at the sol-gel transition with a percolation dynamic model via co...
Abstract — Mechanicalmeasurements done in the reaction bath, near gelation threshold, lead to the fo...
Herewith we report on the measurements of the time evolution of the fluorescence yield and the Rayle...
We consider a polymer melt, with polymerization index N and a fraction p of cross linked monomers, f...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a polymer melt, with polymerization index N and a fraction p of cross linked monomers, f...
We study the elasticity behaviour at the sol-gel transition with a percolation dynamic model via com...
Nature allows polymers to pass through the gel point with striking simplicity and elegance. However,...
ABSTRACT We report experimental data on gel fraction, gel equilibrium swelling, sol intrinsic viscos...
We develop a percolation model motivated by recent experimental studies of gels with active network ...
We develop a percolation model motivated by recent experimental studies of gels with active network ...
The critical behaviour of the elastic constant and the friction coefficient have been measured in th...
The critical behaviour of the elastic constant and the friction coefficient have been measured in th...
We study the elasticity behaviour at the sol-gel transition with a percolation dynamic model via co...
Abstract — Mechanicalmeasurements done in the reaction bath, near gelation threshold, lead to the fo...
Herewith we report on the measurements of the time evolution of the fluorescence yield and the Rayle...
We consider a polymer melt, with polymerization index N and a fraction p of cross linked monomers, f...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a particular case of vulcanization of polymer chains in a semi dilute solution where a c...
We consider a polymer melt, with polymerization index N and a fraction p of cross linked monomers, f...
We study the elasticity behaviour at the sol-gel transition with a percolation dynamic model via com...
Nature allows polymers to pass through the gel point with striking simplicity and elegance. However,...
ABSTRACT We report experimental data on gel fraction, gel equilibrium swelling, sol intrinsic viscos...
We develop a percolation model motivated by recent experimental studies of gels with active network ...
We develop a percolation model motivated by recent experimental studies of gels with active network ...