Max-Planck-Institut für Mikrostrukturphysik,

Microprocesses of metal dusting on iron-nickel alloys and their dependence on the alloy composition E. Pippel*, J. Woltersdorf and H. J. Grabke Metal dusting of iron proceeds via the formation and disinte-gration of the metastable carbide Fe3C, and the resulting fine Fe particles in the coke further catalyse carbon deposition. By contrast, nickel disintegrates directly, and larger grains are released. As revealed by TEM and AEM techniques, in both cases the disinte-gration proceeds by inward growth of thin graphite filaments, the atomic basal planes of which being oriented perpendicular to the surface thus effecting a high reactivity at the growth front. Consequently, successive alloying of iron with nickel should lead to a change over from one disintegration mechanism to the other, and, in fact, we could evidence that the carbide formation takes place only up to a nickel content of about 5 wt.%. Already at a Ni concentration of 10 wt. % a direct disintegration of the metal pro-ceeds, as it is typical for pure nickel. Furthermore, in all investi-gated Ni-Fe alloys a surface-near enrichment of Ni was observed which indicates a selective corrosion of Fe, decreasing with increas-ing Ni content of the basic alloy.