Add to ORKGA model of electrode reaction preceded by a first-order chemical reaction under chronoampero-metric conditions on spherical electrodes has been developed. A general solution applying to all values of equilibrium constants, including very small ones, was obtained by numerical inte-gration. Well-known analytical solutions for steady-state and near-steady-state conditions and for pure kinetic currents were shown to be special cases of the general solution. The conditions for their application are given. Key words CE mechanism chronoamperometry spherical electrodes microelectrodes * Author to whom correspondence should be addressed. (E-mail
Using geometric models based on one-dimensional transport at spheres and cylinders, three methods fo...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
The complete theory corresponding to a CE mechanism when applying cyclic chronopotentiometry to a sp...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
Electrochemical processes involving a follow-up homogeneous chemical reaction are very common and la...
A mathematical model of CE reaction schemes under first or pseudo-first order conditions with differ...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A general computational strategy is presented for the calculation of the chronoamperometric response...
A general computational strategy is presented for the calculation of the chronoamperometric response...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A second-order (nonlinear) model is derived for steady-state kinetics of an EC' (catalytic electroch...
Using geometric models based on one-dimensional transport at spheres and cylinders, three methods fo...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
The complete theory corresponding to a CE mechanism when applying cyclic chronopotentiometry to a sp...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
A model of electrode reaction preceded by a first-order chemical reaction under chronoamperometric c...
Electrochemical processes involving a follow-up homogeneous chemical reaction are very common and la...
A mathematical model of CE reaction schemes under first or pseudo-first order conditions with differ...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A general computational strategy is presented for the calculation of the chronoamperometric response...
A general computational strategy is presented for the calculation of the chronoamperometric response...
A powerful, unified, and simplifying mathematical approach for the theoretical treatment of first-or...
A second-order (nonlinear) model is derived for steady-state kinetics of an EC' (catalytic electroch...
Using geometric models based on one-dimensional transport at spheres and cylinders, three methods fo...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...
International audienceIn the first part of this work, we proposed the so-called GS-, FE- and FT-PSCA...