New air-stable ruthenium(II) complexes that contain the aryldiamine ligand [C6H3(CH2-NMe2)(2)-2,6](-) (NCN) are described. These complexes are [RuCl{eta(2)-C,N-C6H3(CH2NMe2)(2)-2,6}(eta(6)-C10H14)] (2; C10H14 = p-cymene = C6H4Me-Pr-i-4), [Ru{eta(2)-C,N-C6H3(CH2NMe2)(2)-2,6}(eta(5)-C5H5)(PPh3)] (5), and their isomeric forms [RuCl{eta(2)-C,N-C6H3(CH2NMe2)(2)-2,4}(eta(6)-C10H14)] (3) and [Ru{eta(2)-C,N-C6H3(CH2NMe2)(2)-2,4}(eta(5)-C5H5)(PPh3)] (6), respectively. Complex 2 has been prepared from the reaction of [Li(NCN)](2) with [RuCl2(eta(6)-C10H14)](2), whereas complex 5 has been prepared by the treatment of [RuCl{eta(3)-N,C,N-C6H3(CH2NMe2)(2)-2,6}(PPh3)] (4) with [Na(C5H5)](n). Both 2 and 5 are formally 18-electron ruthenium(II) complexes in...
5,7,12,14-Tetraazapentacene-6,13-quinone (L) reacts with 2 equiv of [Ru(acac)(2)(CH3CN)(2)] to form ...
The reaction of [RuCl2(p-cymene)](2) with in situ deprotonated NHC precursor 1,3-bis(biphenyl-2-yl)i...
The reaction of Ru(Et2dtc)2(DMSO)2 (Et2dtc = N,N-diethyldithiocarbamate; DMSO = dimethyl sulfoxide) ...
New air-stable ruthenium(II) complexes that contain the aryldiamine ligand [C6H3(CH2NMe2)2-2,6]- (NC...
Reactions of the bis-isopropyl and bis-cyclohexyl alkyl Binap ligands, 8 and 9, respectively, with [...
[(eta(6)-C(10)H(14))RuCl(mu-Cl)](2) (eta(6)-C(10)H(14) = eta(6)-p-cymene) was subjected to a bridge-...
Treatment of the various ruthenium(II) salts [Ru(ONO2)(eta-6-1,2-dimethylarene)L2]NO3 and [Ru(O2CCF3...
In the η3-butadienyl complex Ru{η3-C(CN)2CPhC[double bond, length as m-dash]C(CN)2}(PPh3)Cp 1, which...
The complex [(eta(6)-C6Me6)Ru(mu-Cl)Cl](2) 1 react with sodium salts of beta-diketonato ligands in m...
The reaction of the complexes ctc-[Ru(II)L(2)Cl(2)] (L = arylazopyridine, RC(6)H(4)N=NC5H4N, where R...
Reaction of [Ru(Me 3tacn)(PMe 3) 2(O 2CCF 3)]PF 6 with one equivalent of t-BuNC or 4-cyano-1-isocyan...
Reaction of [{Ru(eta (3):eta (3)-C10H16)(mu -Cl)Cl}(2)] with 4-cyanopyridine (referred hereafter as ...
Tridentate ligands with [P,N,O] donor sets, prepared either by the condensation of 2-(diphenylphosph...
By using [RuCl2(h4-COD)]n , COD/cycloocta-1,5-diene (C8H12) or [RuCl2(h6-cym)]2, cym/p-methyl-isopro...
The reaction of excess 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) with Ru(η2-RL)(PPh3...
5,7,12,14-Tetraazapentacene-6,13-quinone (L) reacts with 2 equiv of [Ru(acac)(2)(CH3CN)(2)] to form ...
The reaction of [RuCl2(p-cymene)](2) with in situ deprotonated NHC precursor 1,3-bis(biphenyl-2-yl)i...
The reaction of Ru(Et2dtc)2(DMSO)2 (Et2dtc = N,N-diethyldithiocarbamate; DMSO = dimethyl sulfoxide) ...
New air-stable ruthenium(II) complexes that contain the aryldiamine ligand [C6H3(CH2NMe2)2-2,6]- (NC...
Reactions of the bis-isopropyl and bis-cyclohexyl alkyl Binap ligands, 8 and 9, respectively, with [...
[(eta(6)-C(10)H(14))RuCl(mu-Cl)](2) (eta(6)-C(10)H(14) = eta(6)-p-cymene) was subjected to a bridge-...
Treatment of the various ruthenium(II) salts [Ru(ONO2)(eta-6-1,2-dimethylarene)L2]NO3 and [Ru(O2CCF3...
In the η3-butadienyl complex Ru{η3-C(CN)2CPhC[double bond, length as m-dash]C(CN)2}(PPh3)Cp 1, which...
The complex [(eta(6)-C6Me6)Ru(mu-Cl)Cl](2) 1 react with sodium salts of beta-diketonato ligands in m...
The reaction of the complexes ctc-[Ru(II)L(2)Cl(2)] (L = arylazopyridine, RC(6)H(4)N=NC5H4N, where R...
Reaction of [Ru(Me 3tacn)(PMe 3) 2(O 2CCF 3)]PF 6 with one equivalent of t-BuNC or 4-cyano-1-isocyan...
Reaction of [{Ru(eta (3):eta (3)-C10H16)(mu -Cl)Cl}(2)] with 4-cyanopyridine (referred hereafter as ...
Tridentate ligands with [P,N,O] donor sets, prepared either by the condensation of 2-(diphenylphosph...
By using [RuCl2(h4-COD)]n , COD/cycloocta-1,5-diene (C8H12) or [RuCl2(h6-cym)]2, cym/p-methyl-isopro...
The reaction of excess 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) with Ru(η2-RL)(PPh3...
5,7,12,14-Tetraazapentacene-6,13-quinone (L) reacts with 2 equiv of [Ru(acac)(2)(CH3CN)(2)] to form ...
The reaction of [RuCl2(p-cymene)](2) with in situ deprotonated NHC precursor 1,3-bis(biphenyl-2-yl)i...
The reaction of Ru(Et2dtc)2(DMSO)2 (Et2dtc = N,N-diethyldithiocarbamate; DMSO = dimethyl sulfoxide) ...