Summary

The reduction of carbon dioxide by hydrogen is catalyzed by K[Ru”‘-(EDTA-H)Cl] * 2Hz0 in aqueous medium at milder pressures (1- 4 atm CO2 or H,) and 40 “C. The reduction of CO?, gives formic acid and formaldehyde as the initial reaction products, which later decompose to give CO and H,O as the final products. The rates of formation of formic acid and formaldehyde exhibited first-order dependence with respect to catalyst and dissolved CO * and Hz concen-trations, respectively. The rates of decomposition of formic acid and form-aldehyde studied under the same reaction conditions also showed first-order dependence with respect to catalyst and substrate concentrations, respec-tively. The effect of temperature on the rates of formation and decomposi-tion of formic acid and formaldehyde was also studied in the temperature range 30- 50 “C, and from the Arrhenius plots activation energies were evaluated. Based on the kinetic data, a mechanism is proposed for the formation of formic acid and formaldehyde and their decomposition to CO and HzO, the end products of the reverse water-gas shift reaction