STRUCTURAL MODEL FOR BENZIDINE-VERMICULITE

Abstract A combination of X-ray diffraction, infrared, and chemical data has established that the ion exchange of vermiculite with singly charged benzidine cations in an aqueous olution at pH 1.6 results in a black, highly ordered benzidine-vermiculite intercalate. The intercalate has a basal spacing of 19.25/~ and a primitive unit cell with "a " and "b " edges parallel and equal to those of vermiculite. The number of benzidine molecules per cell is equal to its electric harge. In this structure the benzidine molecules are steeply inclined to the silicate surfaces and close-packed within domains. The domains contain alternating rows of benzidine cations; from row to row the planes are either approximately parallel or perpendicular to the (120) plane, but along any one row the planes of the aromatic rings are parallel to each other. Hy-drogen bonding operates between amine nitrogens and surface oxygens. Key Words--Benzidine, Hydrogen bonding, Intercalation, Vermiculite, X-ray diffraction