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Loop heat pipes (LHPs) are heat transfer devices whose operating principle is based on the evaporation/condensation of a working fluid, and which use the capillary pumping forces to ensure the fluid circulation. Their major advantages as compared to heat pipes are an ability to operate against gravity and a greater maximum heat transport capability. In this paper, a literature review is carried out in order to investigate how various parameters affect the LHP operational characteristics. This review is based on the most recent published experimental and theoretical studies. After a reminder of the LHP operating principle and thermodynamic cycle, their operating limits are described. The LHP thermal resistance and maximum heat transfer capability are affected by the choice of the working fluid, the fill charge ratio, the porous wick geometry and thermal properties, the sink and ambient temperature levels, the design of the evaporator and compensation chamber, the elevation and tilt, the presence of non-condensable gases, the pressure drops of the fluid along the loop. The overall objective for this paper is to point the state-of-the-art for the related technology for future design and applications, where the constraints related to the LHPs are detailed and discussed. © 2006 Elsevier Masson SAS. All rights reserved