Hysteresis Caused by Water Molecules in Carbon Nanotube Field-Effect Transistors. Nano Lett

Carbon nanotube field-effect transistors commonly comprise nanotubes lying on SiO2 surfaces exposed to the ambient environment. It is shown here that the transistors exhibit hysteresis in their electrical characteristics because of charge trapping by water molecules around the nanotubes, including SiO2 surface-bound water proximal to the nanotubes. Hysteresis persists for the transistors in vacuum since the SiO2-bound water does not completely desorb in vacuum at room temperature, a known phenomenon in SiO2 surface chemistry. Heating under dry conditions significantly removes water and reduces hysteresis in the transistors. Nearly hysteresis-free transistors are obtainable by passivating the devices with polymers that hydrogen bond with silanol groups on SiO2 (e.g., with poly(methyl methacrylate) (PMMA)). However, nanotube humidity sensors could be explored with suitable water-sensitive coatings. The results may have implications to field-effect transistors made from other chemically derived materials. The interaction between single-walled carbon nanotubes (SWNTs) and molecular species in the environment can significantly affect the electrical properties of nanotube devices.1 This effect can be exploited for nanoscale chemical sensors,2,3 but is not desired for nanotube-based field-effect transistors (FETs)4-13 potentially applied to future electronics