NOT PROTECTED BY U.S. COPYRIGHT Modeling of Micro- and Macrosegregation and Freckle Formation in Single-Crystal Nickel-Base Superalloy Directional Solidification

The formation of macrosegregation and freckles by multicomponent thermosolutal convection during the directional solidification of single-crystal Ni-base superalloys is numerically simulated. The model links a previously developed thermodynamic phase equilibrium subroutine with an existing code for simultaneously solving the macroscopic mass, momentum, energy, and species conservation equa-tions for solidification of a multicomponent alloy. Simulation results are presented for a variety of casting speeds and imposed thermal gradients and for two alloy compositions. It is found that for a given alloy composition, the onset of convection and freckle formation occurs at a critical primary dendrite arm spacing, which agrees well with previous experimental findings. The predicted number and shape of the freckle chains in the unstable cases also agree qualitatively with experimental observations. Finally, it is demonstrated how the onset and nature of convection and macrosegre-gation vary with alloy composition. It is concluded that the present model can provide a valuable tool in predicting freckle defects in directional solidification of Ni-base superalloys. I